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Aliovalent-Doping Effects on the Surface Activity of Mesoporous CeO2 towards Nerve Agent Simulant DMMP Decomposition

Tianyu Li, Lucas Algrim, Monica McEntee, Roman Tsyshevsky, Matthew Leonard, Erin M. Durke, Christopher Karwacki, Maija M. Kuklja, Michael R. Zachariah, and Efrain E. Rodriguez​

Orbital Contribution to Paramagnetism and Noninnocent Thiophosphate Anions in Layered Li2MP2S6 Where M = Fe and Co

Timothy J. Diethrich, Peter Y. Zavalij, Stephanie Gnewuch, and Efrain E. Rodriguez

Polar Ferromagnetic Metal by Intercalation of Metal–Amine Complexes

Huafei Zheng, Brandon C. Wilfong, Daniel Hickox-Young, James M. Rondinelli, Peter Y. Zavalij, and Efrain E. Rodriguez

Crystal field-induced lattice expansion upon reversible oxygen uptake/release in YbMnxFe2-xO4

Tianyu Li, Rishvi Jayathilake, Lahari Balisetty, Yuan Zhang, Brandon Wilfong, Timothy J. Diethrich, and Efrain E. Rodriguez

Full list of publications


92. Matthew B. Leonard, Eric Bruni, Morgan Hall, Tianyu Li, Efrain E. Rodriguez, and Erin M. Durke “Experimental Study of the Adsorption and Decomposition of Sarin on Dry Copper(II) Oxide”, The Journal of Physical Chemistry Letters 0, 13.

[DOI: 10.1021/acs.jpclett.2c03187]

91. Li, T.; Algrim, L.; McEntee, M.; Tsyshevsky, R.; Leonard, M.; Durke, E. M.; Karwacki, C.; Kuklja, M. M.; Zachariah, M. R.; Rodriguez, E. E. “Aliovalent-Doping Effects on the Surface Activity of Mesoporous CeO2 toward Nerve Agent Simulant DMMP Decomposition”, The Journal of  Physical Chemistry C, 2022, available online. [DOI:10.1021/acs.jpcc.2c04853]

90. Leonard, M.; Li, T.; Kramer, M.; McDonnell, S. M.; Vedernikov, A. N.; Rodriguez, E. E.*, “Synthesis of Ordered Mesoporous Cerium Doped Titanium Oxide for Toxic Chemical Filtration”, Journal of Hazardous Materials, 2022, 15, 129536. [DOI:10.1016/j.jhazmat.2022.129536]

89. Diethrich, T. J.; Gnewuch, S.; Dold, K. G.; Taddei, K.; Rodriguez, E. E.*, “Tuning Magnetic Symmetry and Properties in the Olivine Series Li1-xFexMn1-xPO4 through Selective Delithiation” Chemistry of Materials, 2022, 34, 5039–5053. [DOI:10.1021/acs.chemmater.2c00372]

88. Campbell, D. J.; Wilfong, B.; Zic, M. P.; Levy, G.; Na, M. X.; Pedersen, T. M.; Gorovikov, S.; Zavalij, P. Y.; Zhdanovich, S.; Damascelli, A.; Rodriguez, E. E.; Paglione, J., “Physical properties and electronic structure of single-crystal KCo2As2” Physical Review Materials, 2022, 6, 045003. [DOI: 10.1103/PhysRevMaterials.6.045003]

87. Shaw, T. E.; Diethrich, T. J.; Stern, C. L.; Scott, B. L.; Jurca, T; Gilbert, T. M.; Sattelberger, A. P., "Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum( iv ) chloride and tungsten( iv ) chloride", Dalton Transactions 2022, 20. [DOI:10.1039/d2dt00787h]

86. Li, T.; Tsyshevsky, R.; McEntee, M.; Durke, E. M.; Karwacki, C.; Rodriguez, E. E., Kuklja, M. M., “Detection of Sarin Reactivity on Titania Nanomaterials: Understanding FundamentalsACS Applied Nano Materials, 20225, 6659–6670. [DOI: 10.1021/acsanm.2c00693]

85. A. McDannald, M. Frontzek, A. T. Savici, M. Doucet, E. E. Rodriguez, K. Meuse, J. Opsahl-Ong, D. Samarov, I. Takeuchi, A. G. Kusne, and W. Ratcliff, “On-the-fly autonomous control of neutron diffraction via physics-informed bayesian active learningApplied Physics Reviews, 2022, 9, 021408.  [DOI:10.1063/5.0082956]

84. Li, T.; Jayathilake, R.; Balisetty, L.; Zhang, Y.; Wilfong, B.; Diethrich, T. J.; Rodriguez, E. E.*, "Crystal field-induced lattice expansion upon reversible oxygen uptake/release in YbMnxFe2-xO4”, Materials Advances, 2022, 3(2), 1087-110. [DOI:10.1039/D1MA00822F]

83. Li, T.; Rodriguez, E. E.*, “Mesoporous perovskite titanates via hydrothermal conversion”, Chemical Communications, 2022, 58, 783-786. [DOI: 10.1039/D1CC05343D]

82. Lane, H.  Rodriguez, E. E.; Walker, H.C.; Niedermayer, Ch.; Stuhr, U.; Bewley, R.I.; Voneshen, D.J.; Green, M.A.; Rodriguez-Rivera, J.A.; Fouquet, P.; Cheong, S.-W.; Attfield, J. P.; Ewings, R. A.; Stock, C., “Metastable antiphase boundary ordering in CaFe2O4”, Physical Review B, 2021, 104(1), 104404. [DOI: 10.1103/PhysRevB.104.104404]

81. Li, T.; Tsyshevsky, R.; Algrim, L.; McEntee, M.; Durke, E. M.; Eichhorn, B.; Zachariah, M. R.; Kuklja, M. M.;. Rodriguez, E. E.*, “Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO2”, ACS Applied Materials & Interfaces 2021, 13(45), 54597-54609. [DOI: 10.1021/acsami.1c16668].

80. Shaw, T. E.; Diethrich, T. J.; Scott, B. L.; Gilbert, T. M.; Sattelberger, A. P.; Jurca, T, ""MoCl3(dme)” Revisited: Improved Synthesis, Characterization, and X‑ray and Electronic Structures", Inorganic Chemistry 2021, 60(16), 12218-12225. [DOI:10.1021/acs.inorgchem.1c01398]

79. Zheng, H.; Wilfong, B.; Hickox-Young, D.; Rondinelli, J.; Zavalij, P. Y.; Rodriguez, E. E.* “A Polar Ferromagnetic Metal by Intercalation of Metal-amine Complexes,” Chemistry of Materials, 2021, 33, 4936-4947. [DOI: 10.1021/acs.chemmater.1c00540]

78. Diethrich, T. J.; Gnewuch, S.; Zavalij, P.Y.; Rodriguez, E. E.* “Orbital contribution to paramagnetism and non-innocent thiophosphate anions in layered Li2MP2S6 where M = Fe, Co,” Inorganic Chemistry, 2021, 60, 10280-10290. [DOI: 10.1021/acs.inorgchem.1c00710]

77. Gillard, C.; Zhou, X.; Avdeev, M.; Rodriguez, E. E.; Sharma, Neeraj “On the electrochemical phase evolution of cobalt selenide in alkali ion batteries,” Inorganic Chemistry, 2021, 60, 7150-7160. [DOI: 10.1021/acs.inorgchem.1c00226]

76. Campbell, D. J.; Collini, J.; Slawinska, J.; Autieri, C.; Wang, L.; Wang, K.; Wilfong, B.; Eo, Y.S.; Neves, P.; Graf, D.; Rodriguez, E. E.; Butch, N. P.; Buongiorno Nardelli, M.; Paglione, J., “Topologically-Driven Linear Magnetoresistance in Helimagnetic FeP,” npj Quantum Materials, 2021, 6, 38. [DOI: 10.1038/s41535-021-00337-2]

75. Trainer C.; Songvilay, M.; Qureshi, N.; Stunault, A.; Yim, C. M.; Rodriguez, E. E.; Heil, C.; Tsurkan, V.; Green, M. A.;  Loidl, A.; Wahl, P. and Stock, C., “Magnetic surface reconstruction in the van der Waals antiferromagnet Fe1+xTe,” Physical Review B, 2021, 103, 024406.[DOI: 10.1103/PhysRevB.103.024406]

74. Guiton, B. S.; Stefik, M.; Augustyn, V.; Banerjee, S.; Bardeen, C. J.; Bartlett, B. M.; Li, J.; López-Mejías, V.; MacGillivray, L. R.; Morris, A.; Rodriguez,  E. E.; Samia, A.C. S.;  Sun, H.;  Sutter P.;  Talham D. R., “Frontiers in hybrid and interfacial materials chemistry research,” Materials Research Bulletin, 2020, 45, 951-964. [DOI: 10.1557/mrs.2020.271]

73. Gnewuch, S.; Rodriguez, E. E,*"Distinguishing the intrinsic antiferromagnetism in polycrystalline LiCoPO4 and LiMnPO4 Olivines.” Inorganic Chemistry, 2020, 59, 5883-5895. [DOI: 10.1021/acs.inorgchem.9b03545]

72. Cooley, J. A.; Bocarsly, J. D.; Schueller, E. C.; Levin, E. E.; Rodriguez, E. E.; Huq, A.; Lapidus, S. H.; Wilson, S. D.; Seshadri, R. “Evolution of noncollinear magnetism in magnetocaloric MnPtGa”, Physical Review Materials, 2020, 4, 044405.

[DOI: 10.1103/PhysRevMaterials.4.044405]
71. Zhou, X.; Wang, L.; Fan, X.; Wilfong, B.; Liou, S.-C.; Wang, Y.; Zheng, H.; Feng, Z.; Wang, C.; Rodriguez, E. E,* "Isotope Effect between H2O and D2O in Hydrothermal Synthesis", Chemistry of Materials, 2020, 32, 765. [DOI: 10.1021/acs.chemmater.9b04121]

70. Wilfong, B.; Zhou, X.; Zheng, H.; Babra, N.; Brown, C.; Lynn, J. W.; Taddei, K.; Paglione, J.; Rodriguez, E. E,* "Long-range magnetic order in hydroxide-layer-doped (Li1-x-yFexMnyOD)FeSe", Physical Review Materials, 2020, 4, 034803.

[DOI: 10.1103/PhysRevMaterials.4.034803]

69. DePablo, J. J.; Jackson, N. E.; Webb, M.; Chen, L.-Q.; Moore, J.; Rodriguez, E. E. et al. “New frontiers for the materials genome initiative” NPJ Computational Materials, 2019, 5, 41. [DOI: 10.1038/s41524-019-0173-4]

68. Tosado, J.; Chen, W.C.; Gnewuch, S.; Hasaan, T.; Dax, T.; Rodriguez, E. E.*, "Small-angle neutron polarimetry apparatus (SANPA): Development at the NIST Center for Neutron Research " Review of Scientific Instruments, 2019, 90, 063303. [DOI: 10.1063/1.5091110]

67. Tosado, J.; Chen, W.C.; Rodriguez, E. E.*, "A strategy for handling aberration in Spherical Neutron Polarimetry " Journal of Physics: Conference Series, 2019, 1316, 012015. [DOI: 10.1088/1742-6596/1316/1/012015]

66. Virtue, A.; Zhou, X.; Wilfong, B.; Lynn, J. W.; Taddei, K.; Zavalij, P.; Wang, L.; Rodriguez, E. E.*, "Magnetic order effects on the electronic structure of KMMnS2 (M=Cu,Li) with the ThCr2Si2-type structure" Physical Review Materials, 2019, 3, 044411.

[DOI: 10.1103/PhysRevMaterials.3.044411]

65. Li, T.; Jayathilake, R.; Taylor, D. D.; Rodriguez, E. E*, "Structural studies of the perovskite series La1-xSrxCoO3-d during chemical looping with methane" Chemical Communications, 2019, 55, 4929. [DOI: 10.1039/C8CC09573F]

64. Trainer, C.; Yim, C. M.; Heil, C.; Giustino, F; Croitori, D.; Tsurkan, V.; Loidl, A.; Rodriguez, E. E.; Stock, C.; Wahl, P., “Manipulating surface magnetic order in iron telluride” Science Advances, 2019, 5, 3478. [DOI: 10.1126/sciadv.aav3478]

63. Gnewuch, S.; Rodriguez, E. E.* “The fourth ferroic order: Current status on ferrotoroidic materials” Journal of Solid State Chemistry, 2019, 271, 175. [DOI: 10.1016/j.jssc.2018.12.035]

62. Wang, X.; Jayathilake, R.; Taylor, D. D.; Rodriguez, E. E, Zachariah, M. R., “Study of C/Doped δ-Bi2O3 Redox Reactions by in Operando Synchrotron X-ray Diffraction: Bond Energy/Oxygen Vacancy and Reaction Kinetics Relationships” Journal of Physical Chemistry C, 2018, 122(16), 8796. [DOI: 10.1021/acs.jpcc.8b01402]

61. Sarte, P. M.; Cowley, R. A.; Rodriguez, E. E.; Stock. C.; et al., “Disentangling orbital and spin exchange interactions for Co2+ on a rocksalt lattice” Physical Review B, 2018, 98, 024415. [DOI: 10.1103/PhysRevB.98.024415]

60. Songvilay, M.; Rodriguez, E. E.; Lindsay, R.; Green, M. A.; Walker, H. C.; Rodriguez-Rivera, J. A.; Stock, C., "Anharmonic Magnon Excitations in Noncollinear and Charge-Ordered RbFe2+Fe3+F6", Physical Review Letters, 2018, 121, 087201. [DOI: 10.1103/PhysRevLett.121.087201]

59. Zhou, X.; Wilfong, B.; Liou, S.-C., Hodovanets, H.; Brown C. M. and Rodriguez, E.E*, "Proton and ammonia intercalation into layered iron chalcogenides", Chemical Communications, 2018, Special Issue on Emerging Investigators 2018. [DOI: 10.1039/C8CC02436G

58. Jayathilake, R.; Levitas, B.; Rodriguez, E. E.*, “In situ diffraction studies on reversible oxygen uptake and release in AFe2O4+δ (A = Lu, Yb, Y, In)”, Journal of Materials Chemistry A, 2018, 6, 4801-4810.  [DOI:10.1039/C7TA09823E]

57. Wilfong, B.; Zhou, X.; Vivanco, H. K.; Campbell, D. J.; Wang, K.; Graf, D.; Paglione, J.; Rodriguez, E. E.*, “Frustrated magnetism in tetragonal CoSe, analogue to superconducting FeSe”, Physical Review B, 2018, 97, 104408.  [DOI:10.1103/PhysRevB.97.104408]

56. Vera Stimpson, L. J.; Rodriguez, E. E.; Brown, C. M.; Stenning, G. B. B; Jura, M.; Arnold, D. C.  “Magnetic ordering in a frustrated bow-tie lattice”, Journal of Materials Chemistry C, 2018, 6, 4541, [DOI: 10.1039/C7TC05187E]

55. Stanev, V; Oses, C.; Kusne, A. G.; Rodriguez, E. E.; Paglione, J.; Curtarolo, S.; Takeuchi, I., “Machine learning modeling of superconducting critical temperature”, npj Computational Materials, 2018, 4, 29, [DOI: 10.1038/s41524-018-0085-8]

54. Stock, C.; Rodriguez, E. E.; Lee, N.; Demmel, F.; Fouquet, P.; Laver, M.; Niedermayer, Ch.; Su, Y.; Nemkosvski, K; Green, M.A.; Rodriguez-Rivera, J. A.; Kim, J.W.; Zhang, L.; Cheong, S.-W., “Orphan spins in the S = 5/2 antiferromagnet CaFe2O4”, Physical Review Letters., 2017, 119, 257204. [DOI:10.1103/PhysRevLett.119.257204]

53. Zhou, X.; Eckberg, C.; Wilfong, B.; Liou, S.-C.; Vivanco, H. K.; Paglione, J.; Rodriguez, E. E.*, “Superconductivity and magnetism in iron sulfides intercalated by metal hydroxides”, Chemical Sciences, 2017, 8, 3781.  [DOI:10.1039/C6SC05268A]

52. Larson, A.; Wilfong, B.; Moetakef, P.; Brown, C. M.; Zavalij, P.; Rodriguez, E. E.*, “Metal–insulator transition tuned by magnetic field in Bi1.7V8O16 hollandite”, Journal of Materials Chemistry C, 2017, 5, 4967. [DOI: 10.1039/C7TC00487G]

51. Zhou, X.; Rodriguez, E. E.*, “Tetrahedral transition metal chalcogenides as functional inorganic materials”, Chemistry of Materials, 2017, 29, 5737. [DOI:10.1021/acs.chemmater.7b01561] Paper part of the Up-and-Coming series.

50. Zhou, X.; Wilfong, B.; Vivanco, H. K.; Paglione, J.; Brown, C. M.; Rodriguez, E. E.*, “Metastable layered cobalt chalcogenides from topochemical deintercalation”, Journal of the American Chemical Society, 2016, 138, 16432.  [DOI: 10.1021/jacs.6b10229]

49. Zhou, X.; Zhou, W.; Udovic, T. J.; Yildrim, T.; Rush, J. J.; Rodriguez, E. E.; Wu, H.*, “Development of potential organic-molecule-based hydrogen storage materials: Converting C-N bond-breaking thermolysis of guanidine to N-H bond-breaking dehydrogenation”, International Journal of Hydrogen Energy, 2016, 41, 18542. [DOI:  10.1016/j.ijhydene.2016.08.129]

48. Liu, L.; Taylor, D. D.; Rodriguez, E. E.; Zachariah, M. R.*, “Influence of transition metal electronegativity on the oxygen storage capacity of perovskite oxides”, Chemical Communications, 2016, 52, 10369. [DOI: 10.1039/C6CC01997H]

47. Wu, H.*; Zhou, X.; Rodriguez, E. E.; Zhou, W.; Udovic, T. J.; Yildrim, T.; Rush, J. J., “A new family of metal borohydride guanidinate complexes: Synthesis, structures and hydrogen-storage properties”, Journal of Solid State Chemistry, 2016, 242, 186.  [DOI: 10.1016/j.jssc.2016.07.013]

46. Taylor, Daniel D.; Schreiber, N.; Levitas, B.; Xu, W.; Whitfield, P.; Rodriguez, E. E.*, “Oxygen storage properties of La1−xSrxFeO3−δ for chemical-looping reactions-an in-situ neutron and synchrotron X-ray study”, Chemistry of Materials, 2016, 28, 3951. 
[DOI: 10.1021/acs.chemmater.6b01274]

45. Vivanco, H. K. and Rodriguez, E. E.*, “The intercalation chemistry of layered iron chalcogenide superconductors”, Journal of Solid State Chemistry, 2016, 242, 3.  [DOI: 10.1016/j.jssc.2016.04.008]

44. Borg, C. K. H.; Zhou, X.; Eckberg, C.; Campbell, D. J.; Saha, S. R.; Paglione, J.; Rodriguez, E. E.* “Strong anisotropy in nearly ideal tetrahedral superconducting FeS single crystals”, Physical Review B, 2016, 93, 094522. [DOI: 10.1103/PhysRevB.93.094522]  Selected for the Editor’s Suggestion

43. Zhou, X.; Borg, C. K. H.; Lynn, J. W.; Saha, S. R.; Paglione, J.; Rodriguez, E. E.* “The preparation and phase diagrams of (7Li1−xFexOD)FeSe and (Li1−xFexOH)FeSe superconductors”, Journal of Materials Chemistry C, 2016,  4, 3934.  

[DOI: 10.1039/C5TC04041H]  Hot Paper for special issue on Emerging Investigators

42. Rodriguez, E. E.*; Cao, H.; Haiges, R.; Melot, B. C.* “Single crystal magnetic structure and susceptibility of CoSe2O5”, Journal of Solid State Chemistry, 2016, 236, 39. [DOI: 10.1016/j.jssc.2015.09.006]

41. Moetakef, P.; Wang, L.; Nunn, A.; Gaskell, K.; Larson, A. M.; Hodges, B. C.; Rodriguez, E. E.* “Tuning the electronic band structure of microporous titanates with the hollandite structure”, Journal of Materials Chemistry A, 2015, 3, 20330. [DOI: 10.1039/C5TA05288B]

40. Lynn, J. W.*; Zhou, X.; Borg, C. K. H.; Saha, S. R.; Paglione, J.; Rodriguez, E. E. “Neutron investigation of the magnetic scattering in an iron-based ferromagnetic superconductor”, Physical Review B, 2015, 92, 060510. [DOI: 10.1103/PhysRevB.92.060510]

39. Stock, C*; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C. “Single to multiquasiparticle excitations in the itinerant helical magnet CeRhIn5”, Physical Review Letters, 2015, 114, 247005. [DOI: 10.1103/PhysRevLett.114.247005]

38. Taylor, D. D.; Schreiber, N. J.; Brown, C. M.; Arevalo-Lopez, A.; Rodriguez, E. E.*  “Stabilization of cubic Sr2FeMoO6 through topochemical reduction”, Chemical Communications, 2015, 51, 12201. [DOI: 10.1039/C5CC04145G]

37. Lennox, R. C.; Taylor, D. D.; Vera Stimpson, L. J.; Stenning, G. B. G; Jura, M.; Price, M. C.; Rodriguez, E. E.; Arnold, D. C.* “PZT-like structural phase transitions in the BiFeO3 - KNbO3 solid solution”, Dalton Transactions, 2015, 44, 10608. [DOI: 10.1039/c5dt00140d]

36. Larson, A. M.; Moetakef, P.; Gaskell,  K. J.;  Brown,  C.;  King,  G.;  Rodriguez,  E.  E.*; “Inducing ferrimagnetism in insulating hollandite Ba1.2Mn8O16”, Chemistry of Materials, 2015, 27, 515. [DOI: 10.1021/cm503801j]

35. Phelan, D.; Rodriguez, E. E.; Bing, Y.; Gao, J.; Ye, Z.; Huang, Q.; Wen, J.; Xu, G.; Stock, C.; Matsuura, M.; Gehring, P. M.* “Phase diagram of the relaxor ferroelectric (1-x) Pb(Mg1/3Nb2/3)O3 + x PbTiO3: A neutron powder diffraction study of the relaxor skin effect.”, Phase Transitions 2015, 88, 283. [DOI: 10.1080/01411594.2014.989226]

34. Decaroli, C; Arevalo-Lopez, A. M.; Woodall, C. H.; Rodriguez, E. E.; Attfield, J. P.; Parker, S. F.; Stock, C.* “(C4H12N2)[CoCl4]: tetrahedrally coordinated Co2+ without the orbital degeneracy” Acta Crystallographica B, 2015, 71, 20. [DOI: 10.1107/S2052520614024809]

33. Moetakef, P.; Larson, A. M.; Hodges, B. C.; Zavalij, P. Gaskell, K. J.; Piccoli, P.; Rodriguez, E. E.*, ”Synthesis and crystal chemistry of microporous titanates Kx(Ti,M)8O16 where M = Sc-Ni.”, Journal of Solid State Chemistry, 2014,  220, 45. [DOI: 10.1016/j.jssc.2014.08.012]

32. Stacey, T. E.; Borg, C. K. H.; Zavalij, P.; Rodriguez, E. E.*, “Magnetically Stabilized Fe8(µ4-S)6S8 Clusters in Ba6Fe25S27”, Dalton Transactions, 2014, 43, 14612. [DOI: 10.1039/C4DT01182A]

31. McCabe, E. E.; Stock, C.; Rodriguez, E. E.; Wills, A. S.; Taylor, J. W.; Evans, J. S. O.*, “Weak spin interactions in Mott insulating La2O2Fe2OSe2”, Physical Review B, 2014, 89, 100402(R).  [DOI: 10.1103/PhysRevB.89.100402]

30. Rondinelli, J. M.; Benedek, N. A.; Freedman, D. E.; Kavner, A.; Rodriguez, E. E.; Toberer, E. S.; Martin, L. W., “Accelerating functional materials discovery”, American Ceramic Society Bulletin, 2013, 92, 14-2.

29. Gaultois, M. W.*; Barton, P. T.; Birkel, C. S.; Misch, L. M..; Stucky, G. D.; Rodriguez, E. E.; Seshadri, R., “Structural disorder, magnetism, electrical and thermoelectric properties of pyrochlore Nd2Ru2O7”, Journal of Physics: Condensed Matter, 2013, 25, 186004.

[DOI:  10.1088/0953-8984/25/18/186004]

Publications before UMD

28. Stock, C.; Rodriguez, E. E.; Lee, N. Green, M. A.; Demmel, R. A.; Ewings, R. A.; Fouquet, P.; Laver, M.; Niedermayer, Y. S.; Nemkovski, K.; Rodriguez-Rivera, J. A.; Cheong, S.-W., “Solitary magnons in the S = 5/2 antiferromagnet CaFe2O4”, Physical Review Letters, 2016, 117, 017201. [DOI: 10.1103/PhysRevLett.117.017201]

27. Stock, C.; Rodriguez, E. E.; Sobolev, O.; Rodriguez-Rivera, J. A.; Ewings, R. A.; Taylor, J. W.; Christianson, A. D.; Green, M. A., “Soft striped magnetic fluctuations competing with superconductivity in Fe1+xTe”, Physical Review B, 2014, 90, 121113(R). 
[DOI: 10.1103/PhysRevB.90.121113]

26. Rodriguez, E. E.; Stock, C.; Sokolov, D. A.; Green, M. A.; Sobolev, O.; Rodriguez-Rivera, J. A.; Cao, H.; Daoud- Aladine, A., “Magnetic and structural properties near the Lifshitz point in Fe1+xTe”, Physical Review B 2013, 88, 165110.  [DOI: 10.1103/PhysRevB.88.165110]

25. Blachowski,  A.;  Ruebenbauer,  K.;  Zajdel,  P.;  Rodriguez,  E.  E.; Green, M. A., “Mossbauer study of the ‘11’ iron-based superconductors parent compound Fe1+xTe”, Journal of Physics: Condensed Matter, 2012, 24, 386006. [DOI: 10.1088/0953-8984/24/38/386006]

24. Stock, C..; Rodriguez, E. E.; Green, M. A., “Spin fluctuations and superconductivity in powders of Fe1+xTe0.7Se0.3”, Physical Review B, 2012, 85, 094507. [DOI: 10.1103/PhysRevB.85.094507]

23. Bhatia, V.; Rodriguez, E. E.; Butch N. P.; Paglione, J.; Green, M. A., “Phase separation and superconductivity in Fe1+xTe0.5Se0.5”, Chemical Communications, 2011, 47, 11297.  [DOI: 10.1039/C1CC13878B]

22. Rodriguez, E. E.; Stock, C.; Hsieh,  P.-Y.;  Butch,  N.  P.;  Paglione,  J;  Green,  M.  A., “Interstitial iron-controlled superconductivity in Fe1+xTe0.7Se0.3”, Chemical Science, 2011, 2, 1782. [DOI: 10.1039/C1SC00114K]

21. Stock, C.; Rodriguez, E. E.; Green, M. A.; Rodriguez-Rivera, J. A., “Gapped spin fluctuations and in- terstitial iron in the Fe1+xTe parent compound”, Physical Review B, 2011, 84, 045124. [DOI: 10.1103/Phys- RevB.84.045124]

20. Rodriguez, E. E.; Stock, C.; Zajdel, P.; Krycka, K. L.; Majkrzak, C. F.; Zavalij, P.; Green, M. A., “Magnetic-crystallographic phase diagram of the superconducting parent compound Fe1+xTe”, Physical Review B, 2011, 84, 064403. [DOI: 10.1103/PhysRevB.84.064403]

19. Rodriguez, E. E.; Stock, C.; Krycka, K. L; Majkrzak, C. F.; Kirshenbaum, K.; Butch, N. P.; Saha, S. R.; Paglione, J.; Green, M. A., “Non-collinear spin-density wave antiferromagnetism in FeAs”, Physical Review B, 2011, 83, 134438.  [DOI: 10.1103/PhysRevB.83.134438]

18. Zajdel, P.; Hsieh, P.-Y.; Rodriguez, E. E.; Butch, N. P.; Magill, J. D.; Paglione, J.; Zavalij, P.; Suchomel, M. R.; Green, M. A., “Phase separation and suppression of the structural and magnetic transitions in superconducting doped iron tellurides Fe1+xTe1−ySy ”, Journal of the American Chemical Society, 2010, 132, 13000. [DOI: 10.1021/ja105279p]

17. Rodriguez, E. E.; Zavalij, P.; Hsieh, P.-Y.; Green, M. A., “Iodine as an oxidant in the topotactic deintercalation of Fe1+xTe”, Journal of the American Chemical Society, 2010, 132, 10006. [DOI: 10.1021/ja104004t]

16. Johnstone, E. V.; Poineau, F.; Starkey, J.; Hartmann, T.; Forster, P.M.; Ma, L.; Hilgar, J.; Rodriguez, E. E.; Farmand, R.; Czerwinski, K. R.; Sattelberger, A. P., “Synthetic and coordination chemistry of the heavier trivalent technetium binary halides: Uncovering technetium triiodide”, Inorganic Chemistry, 2013, 52, 14309. [DOI:  10.1021/ic402278c]

15. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Kennedy, B. J.; Avdeev, M.; Thorogood, G. J.; Carter, M. L.; Singh, D. J.; Seshadri, R.; Cheetham, A. K, “High temperature magnetic ordering in the 4d perovskite SrTcO3”, Physical Review Letters, 2011, 106, 067201.
[DOI: 10.1103/PhysRevLett.106.067201]

14. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Thompson, J. D.; Seshadri, R.; Cheetham, A. K, “Preparation, magnetism and electronic structures of cadmium technetates”, Journal of Materials Chemistry, 2011, 21, 1496. [DOI: 10.1039/c0jm02470h]

13. Melot, B. C.; Darago, L. E.; Seshadri, R.; Goldman, A.; Furman, J. D.; Rodriguez, E. E.; “Magnetic ordering and magnetodielectric phenomena in CoSeO4”, Journal of Physics: Condensed Matter, 2010, 22, 506003. [DOI: 10.1088/0953-8984/22/50/506003]

12. Weck, P. F.; Kim, E.; Poineau, F.; Rodriguez, E. E.; Sattelberger, A. P.; Czerwinski, K. R. “Structural and electronic trends in rare-earth technetates”, Dalton Transactions, 2010, 39, 7207. [DOI: 10.1039/c0dt00212g]

11. Rodriguez, E. E.; Llobet, A.; Proffen, Th.; Melot, B. C.; Seshadri, R.; Littlewood, P. B.; Cheetham, A. K, “The role of static disorder in negative thermal expansion in ReO3”, Journal of Applied Physics, 2009, 109, 114901. [DOI:  10.1063/1.3120783]

10. Poineau, F.; Rodriguez, E. E.; Forster, P. M.; Sattelberger, A. P.; Cheetham, A. K; Czerwinski, K. R., “Preparation of the binary technetium bromides: TcBr3 and TcBr4”, Journal of the American Chemical Society, 2009, 131, 6281.  [DOI: 10.1021/ja808597r]

9. Wilcox, J. D.; Rodriguez, E. E.; Doeff, M. M., “The impact of aluminum and iron substitution on the structure and electrochemistry of Li(Ni0.4Co0.2−yMyMn0.4)O2 materials”, Journal of the Electrochemical Society, 2009, 156, A1011.  [DOI: 10.1149/1.3237100]

8. Shoemaker, D.; Rodriguez, E. E.; Abumohor, I. S.; Proffen, Th.; Seshadri, R.; “Intrinsic exchange bias in ZnxMn3−xO4 solid solutions”, Physical Review B 2009, 80, 144422. [DOI: 10.1103/PhysRevB.80.144422]

7. Weck, P. F.; Kim, E.; Poineau, F.; Rodriguez, E. E.; Sattelberger, A. P.; Czerwinski, K. R., “Technetium (IV) halides predicted by first-principles”, Inorganic Chemistry, 2009, 48, 6555. [DOI: 10.1021/ic900476m]

6. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Czerwinski, K. R.; Seshadri, R.; and Cheetham, A. K, “Preparation and crystal structures of bismuth technetates: a new metal oxide system”, Inorganic Chemistry, 2008, 47, 6281.  [DOI: 10.1021/ic8003273]

5. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Sattelberger, A. P.; Bhattacharjee, J.; Waghmare, U. V.; Hartmann, T.; Cheetham, A. K, “Structural studies of TcO2 by neutron powder diffraction and first- principles calculations”, Journal of the American Chemical Society, 2007, 129, 10244. [DOI: 10.1021/ja0727363]

4. Melot,  B.;  Rodriguez,  E.;  Proffen,  Th.;  Hayward,  M.  A.;  Seshadri,  R.,  “Displacive  disorder in three high-k bismuth oxide pyrochlores”, Materials Research Bulletin, 2006, 41, 961. [DOI: 10.1016/j.materresbull.2006.02.004]

3. Rodriguez, E. E.; Proffen, Th.; Llobet, A.; Mitchell, J. F.; Rhyne, J. J., “Neutron diffraction study of the average and local structure of La0.5Ca0.5MnO3”, Physical Review B 2005, 71, 104430. [DOI: 10.1103/Phys- RevB.71.104430]

2. Ross, C.A.; Castano, T.; Rodriguez, E.; Haratani, S.; Vogeli, B.; Smith, H. I., “Size-dependent switching of multilayer magnetic elements”, Journal of Applied Physics, 2005, 97, 053902. [DOI: 10.1063/1.1850998]

1. Marioni, M.; Bono, D.; Banful, A.B.; del Rosario, M.; Rodriguez, E.; Peterson, B.; Allen, S.M.; O’Handley, R.C., “Pulsed field actuation of Ni-Mn-Ga ferromagnetic shape memory alloy single crystal”, Journal de Physique IV (Paris) 2003, 112, 1001. [DOI:  10.1051/jp4:20031050]

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