To see the full list of publications click here or scroll down. 

Spectroscopic studies of methyl paraoxon decomposition over mesoporous Ce-doped titanias for toxic chemical filtration


Orbital Contribution to Paramagnetism and Noninnocent Thiophosphate Anions in Layered Li2MP2S6 Where M = Fe and Co

Timothy J. Diethrich, Peter Y. Zavalij, Stephanie Gnewuch, and Efrain E. Rodriguez

Polar Ferromagnetic Metal by Intercalation of Metal–Amine Complexes

Huafei Zheng, Brandon C. Wilfong, Daniel Hickox-Young, James M. Rondinelli, Peter Y. Zavalij, and Efrain E. Rodriguez

Crystal field-induced lattice expansion upon reversible oxygen uptake/release in YbMnxFe2-xO4

Tianyu Li, Rishvi Jayathilake, Lahari Balisetty, Yuan Zhang, Brandon Wilfong, Timothy J. Diethrich, and Efrain E. Rodriguez

Full list of publications


90. Leonard, M.; Li, T.; Kramer, M.; McDonnell, S. M.; Vedernikov, A. N.; Rodriguez, E. E.*, “Synthesis of Ordered Mesoporous Cerium Doped Titanium Oxide for Toxic Chemical Filtration”, Journal of Hazardous Materials, 2022, available online. [DOI:10.1016/j.jhazmat.2022.129536]

89. Diethrich, T. J.; Gnewuch, S.; Dold, K. G.; Taddei, K.; Rodriguez, E. E.*, “Tuning Magnetic Symmetry and Properties in the Olivine Series Li1-xFexMn1-xPO4 through Selective Delithiation” Chemistry of Materials, 2022, 34, 5039–5053. [DOI:10.1021/acs.chemmater.2c00372]

88. Campbell, D. J.; Wilfong, B.; Zic, M. P.; Levy, G.; Na, M. X.; Pedersen, T. M.; Gorovikov, S.; Zavalij, P. Y.; Zhdanovich, S.; Damascelli, A.; Rodriguez, E. E.; Paglione, J., “Physical properties and electronic structure of single-crystal KCo2As2” Physical Review Materials, 2022, 6, 045003. [DOI: 10.1103/PhysRevMaterials.6.045003]

87. Shaw, T. E.; Diethrich, T. J.; Stern, C. L.; Scott, B. L.; Jurca, T; Gilbert, T. M.; Sattelberger, A. P., "Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum( iv ) chloride and tungsten( iv ) chloride", Dalton Transactions 2022, 20. [DOI:10.1039/d2dt00787h]

86. Li, T.; Tsyshevsky, R.; McEntee, M.; Durke, E. M.; Karwacki, C.; Rodriguez, E. E., Kuklja, M. M., “Detection of Sarin Reactivity on Titania Nanomaterials: Understanding FundamentalsACS Applied Nano Materials, 20225, 6659–6670. [DOI: 10.1021/acsanm.2c00693]

85. A. McDannald, M. Frontzek, A. T. Savici, M. Doucet, E. E. Rodriguez, K. Meuse, J. Opsahl-Ong, D. Samarov, I. Takeuchi, A. G. Kusne, and W. Ratcliff, “On-the-fly autonomous control of neutron diffraction via physics-informed bayesian active learningApplied Physics Reviews, 2022, 9, 021408.  [DOI:10.1063/5.0082956]

84. Li, T.; Jayathilake, R.; Balisetty, L.; Zhang, Y.; Wilfong, B.; Diethrich, T. J.; Rodriguez, E. E.*, "Crystal field-induced lattice expansion upon reversible oxygen uptake/release in YbMnxFe2-xO4”, Materials Advances, 2022, 3(2), 1087-110. [DOI:10.1039/D1MA00822F]

83. Li, T.; Rodriguez, E. E.*, “Mesoporous perovskite titanates via hydrothermal conversion”, Chemical Communications, 2022, 58, 783-786. [DOI: 10.1039/D1CC05343D]

82. Lane, H.  Rodriguez, E. E.; Walker, H.C.; Niedermayer, Ch.; Stuhr, U.; Bewley, R.I.; Voneshen, D.J.; Green, M.A.; Rodriguez-Rivera, J.A.; Fouquet, P.; Cheong, S.-W.; Attfield, J. P.; Ewings, R. A.; Stock, C., “Metastable antiphase boundary ordering in CaFe2O4”, Physical Review B, 2021, 104(1), 104404. [DOI: 10.1103/PhysRevB.104.104404]

81. Li, T.; Tsyshevsky, R.; Algrim, L.; McEntee, M.; Durke, E. M.; Eichhorn, B.; Zachariah, M. R.; Kuklja, M. M.;. Rodriguez, E. E.*, “Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO2”, ACS Applied Materials & Interfaces 2021, 13(45), 54597-54609. [DOI: 10.1021/acsami.1c16668].

80. Shaw, T. E.; Diethrich, T. J.; Scott, B. L.; Gilbert, T. M.; Sattelberger, A. P.; Jurca, T, ""MoCl3(dme)” Revisited: Improved Synthesis, Characterization, and X‑ray and Electronic Structures", Inorganic Chemistry 2021, 60(16), 12218-12225. [DOI:10.1021/acs.inorgchem.1c01398]

79. Zheng, H.; Wilfong, B.; Hickox-Young, D.; Rondinelli, J.; Zavalij, P. Y.; Rodriguez, E. E.* “A Polar Ferromagnetic Metal by Intercalation of Metal-amine Complexes,” Chemistry of Materials, 2021, 33, 4936-4947. [DOI: 10.1021/acs.chemmater.1c00540]

78. Diethrich, T. J.; Gnewuch, S.; Zavalij, P.Y.; Rodriguez, E. E.* “Orbital contribution to paramagnetism and non-innocent thiophosphate anions in layered Li2MP2S6 where M = Fe, Co,” Inorganic Chemistry, 2021, 60, 10280-10290. [DOI: 10.1021/acs.inorgchem.1c00710]

77. Gillard, C.; Zhou, X.; Avdeev, M.; Rodriguez, E. E.; Sharma, Neeraj “On the electrochemical phase evolution of cobalt selenide in alkali ion batteries,” Inorganic Chemistry, 2021, 60, 7150-7160. [DOI: 10.1021/acs.inorgchem.1c00226]

76. Campbell, D. J.; Collini, J.; Slawinska, J.; Autieri, C.; Wang, L.; Wang, K.; Wilfong, B.; Eo, Y.S.; Neves, P.; Graf, D.; Rodriguez, E. E.; Butch, N. P.; Buongiorno Nardelli, M.; Paglione, J., “Topologically-Driven Linear Magnetoresistance in Helimagnetic FeP,” npj Quantum Materials, 2021, 6, 38. [DOI: 10.1038/s41535-021-00337-2]

75. Trainer C.; Songvilay, M.; Qureshi, N.; Stunault, A.; Yim, C. M.; Rodriguez, E. E.; Heil, C.; Tsurkan, V.; Green, M. A.;  Loidl, A.; Wahl, P. and Stock, C., “Magnetic surface reconstruction in the van der Waals antiferromagnet Fe1+xTe,” Physical Review B, 2021, 103, 024406.[DOI: 10.1103/PhysRevB.103.024406]

74. Guiton, B. S.; Stefik, M.; Augustyn, V.; Banerjee, S.; Bardeen, C. J.; Bartlett, B. M.; Li, J.; López-Mejías, V.; MacGillivray, L. R.; Morris, A.; Rodriguez,  E. E.; Samia, A.C. S.;  Sun, H.;  Sutter P.;  Talham D. R., “Frontiers in hybrid and interfacial materials chemistry research,” Materials Research Bulletin, 2020, 45, 951-964. [DOI: 10.1557/mrs.2020.271]

73. Gnewuch, S.; Rodriguez, E. E,*"Distinguishing the intrinsic antiferromagnetism in polycrystalline LiCoPO4 and LiMnPO4 Olivines.” Inorganic Chemistry, 2020, 59, 5883-5895. [DOI: 10.1021/acs.inorgchem.9b03545]

72. Cooley, J. A.; Bocarsly, J. D.; Schueller, E. C.; Levin, E. E.; Rodriguez, E. E.; Huq, A.; Lapidus, S. H.; Wilson, S. D.; Seshadri, R. “Evolution of noncollinear magnetism in magnetocaloric MnPtGa”, Physical Review Materials, 2020, 4, 044405. [DOI: 10.1103/PhysRevMaterials.4.044405]
71. Zhou, X.; Wang, L.; Fan, X.; Wilfong, B.; Liou, S.-C.; Wang, Y.; Zheng, H.; Feng, Z.; Wang, C.; Rodriguez, E. E,* "Isotope Effect between H2O and D2O in Hydrothermal Synthesis", Chemistry of Materials, 2020, 32, 765. [DOI: 10.1021/acs.chemmater.9b04121]

70. Wilfong, B.; Zhou, X.; Zheng, H.; Babra, N.; Brown, C.; Lynn, J. W.; Taddei, K.; Paglione, J.; Rodriguez, E. E,* "Long-range magnetic order in hydroxide-layer-doped (Li1-x-yFexMnyOD)FeSe", Physical Review Materials, 2020, 4, 034803. [DOI: 10.1103/PhysRevMaterials.4.034803]

69. DePablo, J. J.; Jackson, N. E.; Webb, M.; Chen, L.-Q.; Moore, J.; Rodriguez, E. E. et al. “New frontiers for the materials genome initiative” NPJ Computational Materials, 2019, 5, 41. [DOI: 10.1038/s41524-019-0173-4]

68. Tosado, J.; Chen, W.C.; Gnewuch, S.; Hasaan, T.; Dax, T.; Rodriguez, E. E.*, "Small-angle neutron polarimetry apparatus (SANPA): Development at the NIST Center for Neutron Research " Review of Scientific Instruments, 2019, 90, 063303. [DOI: 10.1063/1.5091110]

67. Tosado, J.; Chen, W.C.; Rodriguez, E. E.*, "A strategy for handling aberration in Spherical Neutron Polarimetry " Journal of Physics: Conference Series, 2019, 1316, 012015. [DOI: 10.1088/1742-6596/1316/1/012015]

66. Virtue, A.; Zhou, X.; Wilfong, B.; Lynn, J. W.; Taddei, K.; Zavalij, P.; Wang, L.; Rodriguez, E. E.*, "Magnetic order effects on the electronic structure of KMMnS2 (M=Cu,Li) with the ThCr2Si2-type structure" Physical Review Materials, 2019, 3, 044411. [DOI: 10.1103/PhysRevMaterials.3.044411]

65. Li, T.; Jayathilake, R.; Taylor, D. D.; Rodriguez, E. E*, "Structural studies of the perovskite series La1-xSrxCoO3-d during chemical looping with methane" Chemical Communications, 2019, 55, 4929. [DOI: 10.1039/C8CC09573F]

64. Trainer, C.; Yim, C. M.; Heil, C.; Giustino, F; Croitori, D.; Tsurkan, V.; Loidl, A.; Rodriguez, E. E.; Stock, C.; Wahl, P., “Manipulating surface magnetic order in iron telluride” Science Advances, 2019, 5, 3478. [DOI: 10.1126/sciadv.aav3478]

63. Gnewuch, S.; Rodriguez, E. E.* “The fourth ferroic order: Current status on ferrotoroidic materials” Journal of Solid State Chemistry, 2019, 271, 175. [DOI: 10.1016/j.jssc.2018.12.035]

62. Wang, X.; Jayathilake, R.; Taylor, D. D.; Rodriguez, E. E, Zachariah, M. R., “Study of C/Doped δ-Bi2O3 Redox Reactions by in Operando Synchrotron X-ray Diffraction: Bond Energy/Oxygen Vacancy and Reaction Kinetics Relationships” Journal of Physical Chemistry C, 2018, 122(16), 8796. [DOI: 10.1021/acs.jpcc.8b01402]

61. Sarte, P. M.; Cowley, R. A.; Rodriguez, E. E.; Stock. C.; et al., “Disentangling orbital and spin exchange interactions for Co2+ on a rocksalt lattice” Physical Review B, 2018, 98, 024415. [DOI: 10.1103/PhysRevB.98.024415]

60. Songvilay, M.; Rodriguez, E. E.; Lindsay, R.; Green, M. A.; Walker, H. C.; Rodriguez-Rivera, J. A.; Stock, C., "Anharmonic Magnon Excitations in Noncollinear and Charge-Ordered RbFe2+Fe3+F6", Physical Review Letters, 2018, 121, 087201. [DOI: 10.1103/PhysRevLett.121.087201]

59. Zhou, X.; Wilfong, B.; Liou, S.-C., Hodovanets, H.; Brown C. M. and Rodriguez, E.E*, "Proton and ammonia intercalation into layered iron chalcogenides", Chemical Communications, 2018, Special Issue on Emerging Investigators 2018. [DOI: 10.1039/C8CC02436G

58. Jayathilake, R.; Levitas, B.; Rodriguez, E. E.*, “In situ diffraction studies on reversible oxygen uptake and release in AFe2O4+δ (A = Lu, Yb, Y, In)”, Journal of Materials Chemistry A, 2018, 6, 4801-4810.  [DOI:10.1039/C7TA09823E]

57. Wilfong, B.; Zhou, X.; Vivanco, H. K.; Campbell, D. J.; Wang, K.; Graf, D.; Paglione, J.; Rodriguez, E. E.*, “Frustrated magnetism in tetragonal CoSe, analogue to superconducting FeSe”, Physical Review B, 2018, 97, 104408.  [DOI:10.1103/PhysRevB.97.104408]

56. Vera Stimpson, L. J.; Rodriguez, E. E.; Brown, C. M.; Stenning, G. B. B; Jura, M.; Arnold, D. C.  “Magnetic ordering in a frustrated bow-tie lattice”, Journal of Materials Chemistry C, 2018, 6, 4541, [DOI: 10.1039/C7TC05187E]

55. Stanev, V; Oses, C.; Kusne, A. G.; Rodriguez, E. E.; Paglione, J.; Curtarolo, S.; Takeuchi, I., “Machine learning modeling of superconducting critical temperature”, npj Computational Materials, 2018, 4, 29, [DOI: 10.1038/s41524-018-0085-8]

54. Stock, C.; Rodriguez, E. E.; Lee, N.; Demmel, F.; Fouquet, P.; Laver, M.; Niedermayer, Ch.; Su, Y.; Nemkosvski, K; Green, M.A.; Rodriguez-Rivera, J. A.; Kim, J.W.; Zhang, L.; Cheong, S.-W., “Orphan spins in the S = 5/2 antiferromagnet CaFe2O4”, Physical Review Letters., 2017, 119, 257204. [DOI:10.1103/PhysRevLett.119.257204]

53. Zhou, X.; Eckberg, C.; Wilfong, B.; Liou, S.-C.; Vivanco, H. K.; Paglione, J.; Rodriguez, E. E.*, “Superconductivity and magnetism in iron sulfides intercalated by metal hydroxides”, Chemical Sciences, 2017, 8, 3781.  [DOI:10.1039/C6SC05268A]

52. Larson, A.; Wilfong, B.; Moetakef, P.; Brown, C. M.; Zavalij, P.; Rodriguez, E. E.*, “Metal–insulator transition tuned by magnetic field in Bi1.7V8O16 hollandite”, Journal of Materials Chemistry C, 2017, 5, 4967. [DOI: 10.1039/C7TC00487G]

51. Zhou, X.; Rodriguez, E. E.*, “Tetrahedral transition metal chalcogenides as functional inorganic materials”, Chemistry of Materials, 2017, 29, 5737. [DOI:10.1021/acs.chemmater.7b01561] Paper part of the Up-and-Coming series.

50. Zhou, X.; Wilfong, B.; Vivanco, H. K.; Paglione, J.; Brown, C. M.; Rodriguez, E. E.*, “Metastable layered cobalt chalcogenides from topochemical deintercalation”, Journal of the American Chemical Society, 2016, 138, 16432.  [DOI: 10.1021/jacs.6b10229]

49. Zhou, X.; Zhou, W.; Udovic, T. J.; Yildrim, T.; Rush, J. J.; Rodriguez, E. E.; Wu, H.*, “Development of potential organic-molecule-based hydrogen storage materials: Converting C-N bond-breaking thermolysis of guanidine to N-H bond-breaking dehydrogenation”, International Journal of Hydrogen Energy, 2016, 41, 18542. [DOI:  10.1016/j.ijhydene.2016.08.129]

48. Liu, L.; Taylor, D. D.; Rodriguez, E. E.; Zachariah, M. R.*, “Influence of transition metal electronegativity on the oxygen storage capacity of perovskite oxides”, Chemical Communications, 2016, 52, 10369. [DOI: 10.1039/C6CC01997H]

47. Wu, H.*; Zhou, X.; Rodriguez, E. E.; Zhou, W.; Udovic, T. J.; Yildrim, T.; Rush, J. J., “A new family of metal borohydride guanidinate complexes: Synthesis, structures and hydrogen-storage properties”, Journal of Solid State Chemistry, 2016, 242, 186.  [DOI: 10.1016/j.jssc.2016.07.013]

46. Taylor, Daniel D.; Schreiber, N.; Levitas, B.; Xu, W.; Whitfield, P.; Rodriguez, E. E.*, “Oxygen storage properties of La1−xSrxFeO3−δ for chemical-looping reactions-an in-situ neutron and synchrotron X-ray study”, Chemistry of Materials, 2016, 28, 3951. 
[DOI: 10.1021/acs.chemmater.6b01274]

45. Vivanco, H. K. and Rodriguez, E. E.*, “The intercalation chemistry of layered iron chalcogenide superconductors”, Journal of Solid State Chemistry, 2016, 242, 3.  [DOI: 10.1016/j.jssc.2016.04.008]

44. Borg, C. K. H.; Zhou, X.; Eckberg, C.; Campbell, D. J.; Saha, S. R.; Paglione, J.; Rodriguez, E. E.* “Strong anisotropy in nearly ideal tetrahedral superconducting FeS single crystals”, Physical Review B, 2016, 93, 094522. [DOI: 10.1103/PhysRevB.93.094522]  Selected for the Editor’s Suggestion

43. Zhou, X.; Borg, C. K. H.; Lynn, J. W.; Saha, S. R.; Paglione, J.; Rodriguez, E. E.* “The preparation and phase diagrams of (7Li1−xFexOD)FeSe and (Li1−xFexOH)FeSe superconductors”, Journal of Materials Chemistry C, 2016,  4, 3934.  [DOI: 10.1039/C5TC04041H]  Hot Paper for special issue on Emerging Investigators

42. Rodriguez, E. E.*; Cao, H.; Haiges, R.; Melot, B. C.* “Single crystal magnetic structure and susceptibility of CoSe2O5”, Journal of Solid State Chemistry, 2016, 236, 39. [DOI: 10.1016/j.jssc.2015.09.006]

41. Moetakef, P.; Wang, L.; Nunn, A.; Gaskell, K.; Larson, A. M.; Hodges, B. C.; Rodriguez, E. E.* “Tuning the electronic band structure of microporous titanates with the hollandite structure”, Journal of Materials Chemistry A, 2015, 3, 20330. [DOI: 10.1039/C5TA05288B]

40. Lynn, J. W.*; Zhou, X.; Borg, C. K. H.; Saha, S. R.; Paglione, J.; Rodriguez, E. E. “Neutron investigation of the magnetic scattering in an iron-based ferromagnetic superconductor”, Physical Review B, 2015, 92, 060510. [DOI: 10.1103/PhysRevB.92.060510]

39. Stock, C*; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C. “Single to multiquasiparticle excitations in the itinerant helical magnet CeRhIn5”, Physical Review Letters, 2015, 114, 247005. [DOI: 10.1103/PhysRevLett.114.247005]

38. Taylor, D. D.; Schreiber, N. J.; Brown, C. M.; Arevalo-Lopez, A.; Rodriguez, E. E.*  “Stabilization of cubic Sr2FeMoO6 through topochemical reduction”, Chemical Communications, 2015, 51, 12201. [DOI: 10.1039/C5CC04145G]

37. Lennox, R. C.; Taylor, D. D.; Vera Stimpson, L. J.; Stenning, G. B. G; Jura, M.; Price, M. C.; Rodriguez, E. E.; Arnold, D. C.* “PZT-like structural phase transitions in the BiFeO3 - KNbO3 solid solution”, Dalton Transactions, 2015, 44, 10608. [DOI: 10.1039/c5dt00140d]

36. Larson, A. M.; Moetakef, P.; Gaskell,  K. J.;  Brown,  C.;  King,  G.;  Rodriguez,  E.  E.*; “Inducing ferrimagnetism in insulating hollandite Ba1.2Mn8O16”, Chemistry of Materials, 2015, 27, 515. [DOI: 10.1021/cm503801j]

35. Phelan, D.; Rodriguez, E. E.; Bing, Y.; Gao, J.; Ye, Z.; Huang, Q.; Wen, J.; Xu, G.; Stock, C.; Matsuura, M.; Gehring, P. M.* “Phase diagram of the relaxor ferroelectric (1-x) Pb(Mg1/3Nb2/3)O3 + x PbTiO3: A neutron powder diffraction study of the relaxor skin effect.”, Phase Transitions 2015, 88, 283. [DOI: 10.1080/01411594.2014.989226]

34. Decaroli, C; Arevalo-Lopez, A. M.; Woodall, C. H.; Rodriguez, E. E.; Attfield, J. P.; Parker, S. F.; Stock, C.* “(C4H12N2)[CoCl4]: tetrahedrally coordinated Co2+ without the orbital degeneracy” Acta Crystallographica B, 2015, 71, 20. [DOI: 10.1107/S2052520614024809]

33. Moetakef, P.; Larson, A. M.; Hodges, B. C.; Zavalij, P. Gaskell, K. J.; Piccoli, P.; Rodriguez, E. E.*, ”Synthesis and crystal chemistry of microporous titanates Kx(Ti,M)8O16 where M = Sc-Ni.”, Journal of Solid State Chemistry, 2014,  220, 45. [DOI: 10.1016/j.jssc.2014.08.012]

32. Stacey, T. E.; Borg, C. K. H.; Zavalij, P.; Rodriguez, E. E.*, “Magnetically Stabilized Fe8(µ4-S)6S8 Clusters in Ba6Fe25S27”, Dalton Transactions, 2014, 43, 14612. [DOI: 10.1039/C4DT01182A]

31. McCabe, E. E.; Stock, C.; Rodriguez, E. E.; Wills, A. S.; Taylor, J. W.; Evans, J. S. O.*, “Weak spin interactions in Mott insulating La2O2Fe2OSe2”, Physical Review B, 2014, 89, 100402(R).  [DOI: 10.1103/PhysRevB.89.100402]

30. Rondinelli, J. M.; Benedek, N. A.; Freedman, D. E.; Kavner, A.; Rodriguez, E. E.; Toberer, E. S.; Martin, L. W., “Accelerating functional materials discovery”, American Ceramic Society Bulletin, 2013, 92, 14-2.

29. Gaultois, M. W.*; Barton, P. T.; Birkel, C. S.; Misch, L. M..; Stucky, G. D.; Rodriguez, E. E.; Seshadri, R., “Structural disorder, magnetism, electrical and thermoelectric properties of pyrochlore Nd2Ru2O7”, Journal of Physics: Condensed Matter, 2013, 25, 186004. [DOI:  10.1088/0953-8984/25/18/186004]

Publications before UMD

28. Stock, C.; Rodriguez, E. E.; Lee, N. Green, M. A.; Demmel, R. A.; Ewings, R. A.; Fouquet, P.; Laver, M.; Niedermayer, Y. S.; Nemkovski, K.; Rodriguez-Rivera, J. A.; Cheong, S.-W., “Solitary magnons in the S = 5/2 antiferromagnet CaFe2O4”, Physical Review Letters, 2016, 117, 017201. [DOI: 10.1103/PhysRevLett.117.017201]

27. Stock, C.; Rodriguez, E. E.; Sobolev, O.; Rodriguez-Rivera, J. A.; Ewings, R. A.; Taylor, J. W.; Christianson, A. D.; Green, M. A., “Soft striped magnetic fluctuations competing with superconductivity in Fe1+xTe”, Physical Review B, 2014, 90, 121113(R). 
[DOI: 10.1103/PhysRevB.90.121113]

26. Rodriguez, E. E.; Stock, C.; Sokolov, D. A.; Green, M. A.; Sobolev, O.; Rodriguez-Rivera, J. A.; Cao, H.; Daoud- Aladine, A., “Magnetic and structural properties near the Lifshitz point in Fe1+xTe”, Physical Review B 2013, 88, 165110.  [DOI: 10.1103/PhysRevB.88.165110]

25. Blachowski,  A.;  Ruebenbauer,  K.;  Zajdel,  P.;  Rodriguez,  E.  E.; Green, M. A., “Mossbauer study of the ‘11’ iron-based superconductors parent compound Fe1+xTe”, Journal of Physics: Condensed Matter, 2012, 24, 386006. [DOI: 10.1088/0953-8984/24/38/386006]

24. Stock, C..; Rodriguez, E. E.; Green, M. A., “Spin fluctuations and superconductivity in powders of Fe1+xTe0.7Se0.3”, Physical Review B, 2012, 85, 094507. [DOI: 10.1103/PhysRevB.85.094507]

23. Bhatia, V.; Rodriguez, E. E.; Butch N. P.; Paglione, J.; Green, M. A., “Phase separation and superconductivity in Fe1+xTe0.5Se0.5”, Chemical Communications, 2011, 47, 11297.  [DOI: 10.1039/C1CC13878B]

22. Rodriguez, E. E.; Stock, C.; Hsieh,  P.-Y.;  Butch,  N.  P.;  Paglione,  J;  Green,  M.  A., “Interstitial iron-controlled superconductivity in Fe1+xTe0.7Se0.3”, Chemical Science, 2011, 2, 1782. [DOI: 10.1039/C1SC00114K]

21. Stock, C.; Rodriguez, E. E.; Green, M. A.; Rodriguez-Rivera, J. A., “Gapped spin fluctuations and in- terstitial iron in the Fe1+xTe parent compound”, Physical Review B, 2011, 84, 045124. [DOI: 10.1103/Phys- RevB.84.045124]

20. Rodriguez, E. E.; Stock, C.; Zajdel, P.; Krycka, K. L.; Majkrzak, C. F.; Zavalij, P.; Green, M. A., “Magnetic-crystallographic phase diagram of the superconducting parent compound Fe1+xTe”, Physical Review B, 2011, 84, 064403. [DOI: 10.1103/PhysRevB.84.064403]

19. Rodriguez, E. E.; Stock, C.; Krycka, K. L; Majkrzak, C. F.; Kirshenbaum, K.; Butch, N. P.; Saha, S. R.; Paglione, J.; Green, M. A., “Non-collinear spin-density wave antiferromagnetism in FeAs”, Physical Review B, 2011, 83, 134438.  [DOI: 10.1103/PhysRevB.83.134438]

18. Zajdel, P.; Hsieh, P.-Y.; Rodriguez, E. E.; Butch, N. P.; Magill, J. D.; Paglione, J.; Zavalij, P.; Suchomel, M. R.; Green, M. A., “Phase separation and suppression of the structural and magnetic transitions in superconducting doped iron tellurides Fe1+xTe1−ySy ”, Journal of the American Chemical Society, 2010, 132, 13000. [DOI: 10.1021/ja105279p]

17. Rodriguez, E. E.; Zavalij, P.; Hsieh, P.-Y.; Green, M. A., “Iodine as an oxidant in the topotactic deintercalation of Fe1+xTe”, Journal of the American Chemical Society, 2010, 132, 10006. [DOI: 10.1021/ja104004t]

16. Johnstone, E. V.; Poineau, F.; Starkey, J.; Hartmann, T.; Forster, P.M.; Ma, L.; Hilgar, J.; Rodriguez, E. E.; Farmand, R.; Czerwinski, K. R.; Sattelberger, A. P., “Synthetic and coordination chemistry of the heavier trivalent technetium binary halides: Uncovering technetium triiodide”, Inorganic Chemistry, 2013, 52, 14309. [DOI:  10.1021/ic402278c]

15. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Kennedy, B. J.; Avdeev, M.; Thorogood, G. J.; Carter, M. L.; Singh, D. J.; Seshadri, R.; Cheetham, A. K, “High temperature magnetic ordering in the 4d perovskite SrTcO3”, Physical Review Letters, 2011, 106, 067201.
[DOI: 10.1103/PhysRevLett.106.067201]

14. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Thompson, J. D.; Seshadri, R.; Cheetham, A. K, “Preparation, magnetism and electronic structures of cadmium technetates”, Journal of Materials Chemistry, 2011, 21, 1496. [DOI: 10.1039/c0jm02470h]

13. Melot, B. C.; Darago, L. E.; Seshadri, R.; Goldman, A.; Furman, J. D.; Rodriguez, E. E.; “Magnetic ordering and magnetodielectric phenomena in CoSeO4”, Journal of Physics: Condensed Matter, 2010, 22, 506003. [DOI: 10.1088/0953-8984/22/50/506003]

12. Weck, P. F.; Kim, E.; Poineau, F.; Rodriguez, E. E.; Sattelberger, A. P.; Czerwinski, K. R. “Structural and electronic trends in rare-earth technetates”, Dalton Transactions, 2010, 39, 7207. [DOI: 10.1039/c0dt00212g]

11. Rodriguez, E. E.; Llobet, A.; Proffen, Th.; Melot, B. C.; Seshadri, R.; Littlewood, P. B.; Cheetham, A. K, “The role of static disorder in negative thermal expansion in ReO3”, Journal of Applied Physics, 2009, 109, 114901. [DOI:  10.1063/1.3120783]

10. Poineau, F.; Rodriguez, E. E.; Forster, P. M.; Sattelberger, A. P.; Cheetham, A. K; Czerwinski, K. R., “Preparation of the binary technetium bromides: TcBr3 and TcBr4”, Journal of the American Chemical Society, 2009, 131, 6281.  [DOI: 10.1021/ja808597r]

9. Wilcox, J. D.; Rodriguez, E. E.; Doeff, M. M., “The impact of aluminum and iron substitution on the structure and electrochemistry of Li(Ni0.4Co0.2−yMyMn0.4)O2 materials”, Journal of the Electrochemical Society, 2009, 156, A1011.  [DOI: 10.1149/1.3237100]

8. Shoemaker, D.; Rodriguez, E. E.; Abumohor, I. S.; Proffen, Th.; Seshadri, R.; “Intrinsic exchange bias in ZnxMn3−xO4 solid solutions”, Physical Review B 2009, 80, 144422. [DOI: 10.1103/PhysRevB.80.144422]

7. Weck, P. F.; Kim, E.; Poineau, F.; Rodriguez, E. E.; Sattelberger, A. P.; Czerwinski, K. R., “Technetium (IV) halides predicted by first-principles”, Inorganic Chemistry, 2009, 48, 6555. [DOI: 10.1021/ic900476m]

6. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Czerwinski, K. R.; Seshadri, R.; and Cheetham, A. K, “Preparation and crystal structures of bismuth technetates: a new metal oxide system”, Inorganic Chemistry, 2008, 47, 6281.  [DOI: 10.1021/ic8003273]

5. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Sattelberger, A. P.; Bhattacharjee, J.; Waghmare, U. V.; Hartmann, T.; Cheetham, A. K, “Structural studies of TcO2 by neutron powder diffraction and first- principles calculations”, Journal of the American Chemical Society, 2007, 129, 10244. [DOI: 10.1021/ja0727363]

4. Melot,  B.;  Rodriguez,  E.;  Proffen,  Th.;  Hayward,  M.  A.;  Seshadri,  R.,  “Displacive  disorder in three high-k bismuth oxide pyrochlores”, Materials Research Bulletin, 2006, 41, 961. [DOI: 10.1016/j.materresbull.2006.02.004]

3. Rodriguez, E. E.; Proffen, Th.; Llobet, A.; Mitchell, J. F.; Rhyne, J. J., “Neutron diffraction study of the average and local structure of La0.5Ca0.5MnO3”, Physical Review B 2005, 71, 104430. [DOI: 10.1103/Phys- RevB.71.104430]

2. Ross, C.A.; Castano, T.; Rodriguez, E.; Haratani, S.; Vogeli, B.; Smith, H. I., “Size-dependent switching of multilayer magnetic elements”, Journal of Applied Physics, 2005, 97, 053902. [DOI: 10.1063/1.1850998]

1. Marioni, M.; Bono, D.; Banful, A.B.; del Rosario, M.; Rodriguez, E.; Peterson, B.; Allen, S.M.; O’Handley, R.C., “Pulsed field actuation of Ni-Mn-Ga ferromagnetic shape memory alloy single crystal”, Journal de Physique IV (Paris) 2003, 112, 1001. [DOI:  10.1051/jp4:20031050]